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As the mineral cools, the crystal structure begins to form and diffusion of isotopes is less easy.At a certain temperature, the crystal structure has formed sufficiently to prevent diffusion of isotopes.Radiometric dating or radioactive dating is a technique used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed.The method compares the abundance of a naturally occurring radioactive isotope within the material to the abundance of its decay products, which form at a known constant rate of decay.The temperature at which this happens is known as the closure temperature or blocking temperature and is specific to a particular material and isotopic system.These temperatures are experimentally determined in the lab by artificially resetting sample minerals using a high-temperature furnace.A particular isotope of a particular element is called a nuclide. That is, at some point in time, an atom of such a nuclide will undergo radioactive decay and spontaneously transform into a different nuclide.This transformation may be accomplished in a number of different ways, including alpha decay (emission of alpha particles) and beta decay (electron emission, positron emission, or electron capture).

Isotopic systems that have been exploited for radiometric dating have half-lives ranging from only about 10 years (e.g., tritium) to over 100 billion years (e.g., samarium-147).After one half-life has elapsed, one half of the atoms of the nuclide in question will have decayed into a "daughter" nuclide or decay product.In many cases, the daughter nuclide itself is radioactive, resulting in a decay chain, eventually ending with the formation of a stable (nonradioactive) daughter nuclide; each step in such a chain is characterized by a distinct half-life.Finally, correlation between different isotopic dating methods may be required to confirm the age of a sample.For example, the age of the Amitsoq gneisses from western Greenland was determined to be Accurate radiometric dating generally requires that the parent has a long enough half-life that it will be present in significant amounts at the time of measurement (except as described below under "Dating with short-lived extinct radionuclides"), the half-life of the parent is accurately known, and enough of the daughter product is produced to be accurately measured and distinguished from the initial amount of the daughter present in the material.

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